Quotation from: General Science

Written by: Bertha M. Clark


221. Wool and Silk Bleaching. Animal fibers like silk, wool, and
feathers, and some vegetable fibers like straw, cannot be bleached by
means of chlorine, because it attacks not only the coloring matter but
the fiber itself, and leaves it shrunken and inferior. Cotton and
linen fibers, apart from the small amount of coloring matter present
in them, contain nothing but carbon, oxygen, and hydrogen, while
animal fibers contain in addition to these elements some compounds of
nitrogen. The presence of these nitrogen compounds influences the
action of the chlorine and produces unsatisfactory results. For animal
fibers it is therefore necessary to discard chlorine as a bleaching
agent, and to substitute a substance which will have a less disastrous
action upon the fibers. Such a substance is to be had in sulphurous
acid. When sulphur burns, as in a match, it gives off disagreeable
fumes, and if these are made to bubble into a vessel containing water,
they dissolve and form with the water a substance known as sulphurous
acid. That this solution has bleaching properties is shown by the fact
that a colored cloth dipped into it loses its color, and unbleached
fabrics immersed in it are whitened. The harmless nature of sulphurous
acid makes it very desirable as a bleaching agent, especially in the
home.

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