Quotation from: General ScienceWritten by: Bertha M. Clark |
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The best laboratory method of securing free chlorine is to heat in a water bath a mixture of hydrochloric acid and manganese dioxide, a compound containing one part of manganese and two parts of oxygen. The heat causes the manganese dioxide to give up its oxygen, which immediately combines with the hydrogen of the hydrochloric acid and forms water. The manganese itself combines with part of the chlorine originally in the acid, but not with all. There is thus some free chlorine left over from the acid, and this passes off as a gas and can be collected, as in Figure 158. Free chlorine is heavier than air, and hence when it leaves the exit tube it settles at the bottom of the jar, displacing the air, and finally filling the bottle.
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